This work examines the effects of photonically induced interband excitations from the d-band to states at the Fermi energy on thermophysical properties in noble metals. The change in the electron population in the d-band and the conduction band causes a change in electron heat capacity and electron-phonon coupling factor, which in turn impacts the evolution of the temperature after pulse absorption and electron thermalization. Expressions for heat capacity and electron-phonon coupling factor are derived for electrons undergoing both inter- and intraband transitions. In noble metals, due to the large d-band to Fermi energy separation, the contributions to electron heat capacity and electron-phonon coupling factor of intra- and interband transitions can be separated. At high absorbed laser fluences and pulse energies greater than the interband transition threshold, the interband and intraband contributions to thermophysical properties differ.
Issue Section:
Technical Briefs
Keywords:
intraband transition,
interband transition,
electron-phonon coupling factor,
short pulsed laser heating,
electronic band structure,
conduction bands,
electron-phonon interactions,
Fermi level,
laser beam effects,
specific heat,
transition metals
Topics:
Electrons,
Excitation,
Heat capacity,
Heat conduction,
Metals,
Phonons,
Temperature,
Density,
Lasers
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